The following questions appeared in the All India Pre-Medical / Pre-Dental Entrance 2008 Examination:
(1) At 10º C the value of the density of a fixed mass of an ideal gas divided by its pressure is x. At 110º C this ratio is
(1) 383x/283
(2) 10x/110
(3) 283x/383
(4) x
We have PV = rT where r is the gas constant for the given mass.
Since the volume V = M/ρ where M is the mass and ρ is the density, we have
P/ρ = rT/M
Since r and M are constants for a given mass of gas, we have
(ρ1/P1) /(ρ2/P2) = T2/T1 where the suffix 1 is for the quantities at temperature 10º C and suffix 2 is for the quantities at temperature 110º.
It is given that (ρ1/P1) = x.
Therefore x/(ρ2/P2) = 383/283 since the temperatures are in degree kelvin.
From this (ρ2/P2) = 283x/383
(2) On a new scale of temperature (which is linear) and called the W scale, the freezing and boiling points of water are 39º W and 239º W respectively. What will be the temperature on the new scale, corresponding to a temperature of 239º C on the Celsius scale?
(1) 117º W
(2) 200º W
(3) 139º W
(4) 78º W
We have 0º C = 39º W and 100º C = 239º W
A temperature difference of 100º C is therefore equivalent to a temperature difference of 200º W. A temperature difference of 1º C is thus equivalent to a temperature difference of 2º W.
Therefore, a temperature 39º C is equal to [39 + (39×2)]º W = 117º W
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